doc: normalize ToC indentation with heading levels in README

PR-URL: https://github.com/nodejs/node/pull/17106


Reviewed-By: Refael Ackermann <refack@gmail.com>
Reviewed-By: Luigi Pinca <luigipinca@gmail.com>
Reviewed-By: Colin Ihrig <cjihrig@gmail.com>
Reviewed-By: Gireesh Punathil <gpunathi@in.ibm.com>
Reviewed-By: Michael Dawson <michael_dawson@ca.ibm.com>